Xenon trioxide | |
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xenon trioxide |
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Identifiers | |
CAS number | 13776-58-4 |
ChemSpider | 21106493 |
Jmol-3D images | Image 1 |
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Properties | |
Molecular formula | XeO3 |
Molar mass | 179.288 g/mol |
Appearance | colourless crystalline solid |
Density | 4.55 g/cm3, solid |
Melting point |
25 °C Violent Decomposition |
Solubility in water | Soluble (with reaction) |
Structure | |
Molecular shape | trigonal pyramidal (C3v) |
Thermochemistry | |
Std enthalpy of formation ΔfH |
402 kJ/mol |
Hazards | |
EU classification | not listed |
NFPA 704 |
0
4
4
OX
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Related compounds | |
Related compounds | Xenon tetroxide Xenic acid |
(verify) (what is: / ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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Infobox references |
Xenon trioxide is an unstable compound of xenon in its +6 oxidation state. It is a very powerful oxidizing agent, and liberates oxygen from water slowly (and xenon), accelerated by exposure to sunlight. It is dangerously explosive upon contact with organic materials. When it detonates, it releases xenon and oxygen gas.
Contents[hide] |
Xenon trioxide is a strong oxidizing agent and can oxidize most substances that are susceptible. However, it is slow-acting and this reduces its usefulness.[1]
When it dissolves in water, an acidic solution of xenic acid is formed:
This solution is stable at room temperature and lacks the explosive properties of xenon trioxide. It oxidises carboxylic acids quantitatively to carbon dioxide and water.[2]
Alternatively, it dissolves in alkaline solutions to form xenates. The HXeO−
4 anion is the predominant species in xenate solutions.[3] These are not stable and begin to disproportionate into perxenates (+8 oxidation state) and xenon and oxygen gas.[4] Solid perxenates containing XeO4−
6 or XeO2−
4 have not yet been isolated; however, XeO3 reacts with inorganic fluorides such as KF, RbF, or CsF to form stable solids of the form MXeO3F.[5]
Hydrolysis of xenon tetrafluoride yields a solution from which colorless XeO3 crystals can be obtained by evaporation.[6] The crystals are stable for days in dry air, but readily absorb water from humid air to form a concentrated solution. The crystal structure is orthorhombic with a = 6.163, b = 8.115, c = 5.234 Å and 4 molecules per unit cell. The density is 4.55 g/cm3.[7]
the crystal structure of XeO3 |
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XeO3 should be handled with great caution. Samples have detonated when undisturbed at room temperature. Dry crystals react explosively with cellulose.[7][8]
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